Today‘s enormous potential for bioenergy from forestry and timber, agricultural raw and residual materials, and organic waste streams can make a major contribution to greenhouse gas emission savings. Specifically, biogas and biomethane upgraded from these sources is essentially sustainably produced renewable natural gas from organic (residual) recyclables with significant energy potential. For this reason, biomethane can make a significant contribution to alternative energies without competing for substrates with the production of food and feed.
Biogas and biomethane production technologies are well developed and economically viable. In the last five to ten years, the efficiency of biomethane upgrading plants has improved significantly, which benefits plant economics.
The gas produced offers a climate-neutral alternative to fossil natural gas and is available with equivalent potential. Necessary electricity for the operation of biogas (upgrading) plants should be provided as CO2-neutral and sustainably as possible. The CO2 captured during biomethane production can be reused industrially or in agricultural production. Unused CO2 does not have a negative impact on the greenhouse effect, as it is not of fossil origin and therefore does not affect the carbon balance in the way that fossil CO2 does.
BIOMETHANE TECHNOLOGY AND INFRASTRUCTURE IN PLACE
Despite existing gas grid infrastructure, the potential of biomethane remains to be fully exploited. In order to reduce greenhouse gas emissions and achieve the set climate targets, biomethane could contribute significantly.. The technology for production and distribution as well as the infrastructure is already in place and available.
Drive technologies for operating vehicles with CNG have been available for years and would only need to be utilized and better marketed. CNG could make a significant contribution to the compliance of fleet emissions of automobile manufacturers. For heavy-duty transport, LNG is the only directly available and economically viable alternative that can meet the requirements of heavy-duty transport.
For LNG, the previously produced biomethane still needs to be liquefied in a further step. The advantages over conventional diesel-powered trucks are obvious:
• Up to 80 percent less CO2 compared to conventional diesel drive
• Approximately 99 percent fewer fine dust particles
• Almost complete reduction of sulfur and nitrogen oxide emissions
• Approximately 50 percent less noise than a comparable diesel engine
In order to produce biomethane or, subsequently, BioLNG, biogas is first produced from organic substrates in a fermentation process. The raw biogas consists of the main components methane and carbon dioxide as well as some other trace gases. The most widespread method of utilization was, and still is, the operation of gas engines or combined heat and power plants to generate electricity and heat. Efficient use is sometimes difficult to achieve here, as the heat generated is often unused and only the electricity is fed into the grid. There are approaches to feed the biogas into own ring associations / interconnected circles and to convert it into electricity at a decentralized location and also to use the heat generated in a targeted manner. However, if raw biogas is upgraded to natural gas quality after biogas production, it can be injected into the regional natural gas grid (if available), stored, and used in many ways regardless of where it is produced.
EFFICIENT BIOGAS UPGRADING USING MEMBRANES
Various technologies are available for separating CO2 from the raw biogas and upgrading it to biomethane. In addition to wellknown technologies such as pressurized water scrubbing, amine scrubbing or pressure swing absorption, membrane technology has become increasingly established in recent years. Thanks to highly efficient and highly selective membranes, it is possible to separate CO2 almost completely from methane in a compact 3-stage process. In some European countries such as France, Switzerland, Italy or Great Britain, membrane processes for biogas upgrading already have a market share of >60%. The advantage of membrane upgrading plants over conventional technologies lies, among other things, in the simplicity of the process and the low maintenance requirements. Of course, the spread of biogas upgrading plants is also influenced by local conditions and regulations as well as national incentives.
Polyimide membranes are the most widely used membrane treatment systems. At the turn of the century, membrane processes were still struggling with a lack of efficiency in terms of yield and selectivity, but this disadvantage has been eliminated by improved process control and improved selectivity thanks to new polymer solutions. Evonik has been producing high-performance polyimide-based plastics since the 1980s, which in turn are processed into high-performance filter materials. In the form of filter bags, these are used very successfully in flue gas cleaning, for example. The basis of this success is, among other things, the high resistance to temperature and pollutants in the flue gas. Filtering or separating is also the main task in the new field of application of this high-performance plastic. The corresponding polyimide and its properties have been modified and further developed accordingly in order to separate gas molecules from each other in a new field of application instead of dusts from flue gas.
EXPERTISE IN POLYMER PROCESSING
The decisive factor here is not only the right material, but also the shape of the filters. For this purpose, it is necessary to spin the polymer into fine hollow fibers and at the same time create properties that enable the separation of gas mixtures such as nitrogen and oxygen or methane and CO2 from each other in a highly efficient and energy-saving manner. Gas separation using membrane technology takes advantage of the different molecular sizes and molecular interactions. Membrane cartridges and modules are manufactured from these hollow fiber membrane bundles, which are used as membrane systems for gas separation.
HIGH PURITY BIOMETHANE WITH 3-STAGE INTERCONNECTION
In the biogas upgrading process, the raw gas is compressed and fed into the interior of the hollow fiber membrane (feed side), the CO2 is mainly directed to the outside (permeate side) due to the properties of the membrane, the methane collects at the end of the membrane (retentate side) in a highly concentrated form. By means of multi-stage interconnection it is possible to achieve a separation of the gas mixture of nearly 100%, usually the methane is available with a purity of >95% and CO2 with a purity of >99%. Depending on the application, higher purities are also possible.
A small part of the biogas upgrading plants with SEPURAN® membranes realized overseas in the last years were equipped with a 2-stage membrane process. The desired product quality can be adjusted as desired, but due to the accompanying methane loss, this interconnection is not sufficient for European standards. On the European continent, the 3-stage treatment process has been used throughout due to the highest efficiency in the use of the SEPURAN® Green Membrane. Here, stage 1 and stage 2 are connected in series, but stage 3 is connected in parallel to stage 1. With this configuration, it was possible for the first time to obtain a very pure product with the highest methane yield using only one compressor.